A simple approach to molecular orbital (MO) theory for heterogeneous diatomic molecules is to show the energy level diagram.
Molecular Orbital Diagram for H-F
Interaction occurs between the 1s orbital on hydrogen and the 2p orbital in fluorine causing the formation of a sigma-bonding and a sigma-antibonding molecular orbital, as shown below
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http://www.science.uwaterloo.ca/~cchieh/cact/applychem/mohetro.html
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